화학공학소재연구정보센터
Powder Technology, Vol.201, No.3, 253-257, 2010
A study of the sintering of diatomaceous earth to produce porous ceramic monoliths with bimodal porosity and high strength
Diatomite powder, a naturally occurring porous raw material, was used to fabricate ceramic materials with bimodal porosity and high strength. The effect of the sintering temperature on the density and porosity of dry pressed diatomite green bodies was evaluated using mercury porosimetry and water immersion measurements. It was found that the intrinsic porosity of the diatomite particles with a pore size around 0.2 mu m was lost at sintering temperatures above 1200 degrees C. Maintaining the sintering temperature at around 1000 degrees C resulted in highly porous materials that also displayed a high compressive strength. Microstructural studies by scanning electron microscopy and energy-dispersive X-ray analysis suggested that the pore collapse was facilitated by the presence of low melting impurities like Na2O and K2O. (C) 2010 Elsevier B.V. All rights reserved.