Powder Technology, Vol.193, No.1, 26-31, 2009
Densification of rare-earth (Lu, Gd, Nd)-doped alumina nanopowders obtained by a sol-gel route under seeding
Rare-earth (RE: Lu, Gd, Nd, 0.10 mol%)-doped alumina nanopowders were prepared by a new sol-gel route using polyhydroxoaluminum (PHA) and RECl3 Solutions under alpha-alumina (similar to 75 nm) seeding. Among the rare-earth dopants studied, Lu yields the most suitable nanopowders for low-temperature densification. The 0.10 mol% Lu-doped nanopowders, which were obtained at a calcination temperature of 900 degrees C under 5 mass % alpha-alumina seeding, consisted of similar to 80-nm alpha-alumina particles and gamma-alumina nanoparticles. Using these Lu-doped alumina nanopowders, fully densified alumina ceramics with a uniform microstructure composed of fine grains with an average size of 0.61 mu m could be obtained at 1400 degrees C by pressureless sintering. Clearly, the Lu-doped nanopowders obtained here represent a viable option for fabricating dense, finer-grained alumina ceramics because an undoped sample with 5 mass% seeds gave a microstructure with an average grain size of 1.78 mu m at 1400 degrees C. (C) 2009 Elsevier B.V. All rights reserved.