Reaction kinetics of phenol synthesis through one-step oxidation of benzene with N2O over Fe-ZSM-5 zeolite

Guanjie Mi; Jianwei Li; Jie Zhang; Biaohua Chen

Korean Journal of Chemical Engineering, Vol.27, No.6, 1700-1706, November, 2010

DOI10.1007/s11814-010-0259-7 Export Citation

Reaction kinetics of phenol synthesis through one-step oxidation of benzene with N2O over Fe-ZSM-5 zeolite

Guanjie Mi, Jianwei Li^†, Jie Zhang, and Biaohua Chen

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

E-mail:

Based on the information from GC-MS on-line measurement and thermodynamic analysis, the reaction network of gas-phase hydroxylation of benzene with nitrous oxide over Fe-ZSM-5 zeolite was systematically investigated. The main reactions and side reactions were identified, and a kinetic reaction network was proposed as follows: benzene+N2O→phenol→CO/CO2. According to the mechanism, the experimental results were interpreted reasonably. The hydroxylation kinetic experiments were carried out in an isothermal integral microreactor under the conditions of n(benzene)/n(N2O)=8-12, T=663-763 K and atmospheric pressure. Based on the reaction network proposed, the parameters in the rate model of power-law were estimated by means of Gauss-Newton optimal method with the Levenberg-Marquardt modifications, and the results were in good agreement with the experimental data.

Keywords:Benzene;N2O;Phenol;Oxidation;Reaction Kinetics;Reaction Network;Fe-ZSM-5 Zeolite

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[3] Battistel E, Tassinari R, Fornaroli M, Bonoldi L, J. Mol. Catal. A-Chem., 202(1-2), 107 (2003)

[4] Hamada R, Shibata Y, Nishiyama S, Tsuruya S, Chem. Phys., 5, 956 (2003)

[5] Kuznetsova NI, Kuznetsova LI, Likholobov VA, Pez GP, Catal. Today, 99(1-2), 193 (2005)

[6] Liu YY, Murata K, Inaba M, J. Mol. Catal. A-Chem., 256(1-2), 247 (2006)

[7] Passoni LC, Cruz AT, Buffon R, Schuchardt U, J. Mol. Catal. A: Chem., 120, 117 (1997)

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[9] Panov GI, Cattech, 4, 18 (2000)

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[18] Uriarte AK, Rodkin MA, Gross MJ, Kharitonov AS, Panov GI, Stud. Surf. Sci. Catal., 110, 857 (1997)

[19] Uriarte AK, Stud. Surf. Sci. Catal., 130, 743 (2000)

[20] Notte PP, Top. Catal., 13, 387 (2000)

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[22] Groen JC, Perez-Ramirez J, Zhu W, J. Chem. Eng. Data, 47, 587 (2002)

[23] Kim MY, Lee KW, Park JH, Shin CH, Lee J, Seo G, Korean J. Chem. Eng., 27(1), 76 (2010)

[24] Hafele M, Reitzmann A, Roppelt D, Emig G, Appl. Catal. A: Gen., 150(1), 153 (1997)

[25] Hafele M, Reitzmann A, Klemm E, Emig G, Stud. Surf. Sci. Catal., 110, 847 (1997)

[26] Centi G, Vazzana F, Catal. Today, 53(4), 683 (1999)

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[34] Benson SW, J. Phys. Chem., 103, 11481 (1999)

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[36] Nguyen HH, Jang NJ, Choi SH, Korean J. Chem. Eng., 26(1), 1 (2009)

[37] de Luis A, Lombrana JI, Varona F, Menendez A, Korean J. Chem. Eng., 26(1), 48 (2009)