화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.27, No.6, 1695-1699, November, 2010
DOI10.1007/s11814-010-0256-x  Export Citation
Simple one-pot synthesis of a mesoporous superacidic catalyst for the dehydration of glycerol to acrolein
Lina Yang, Ji Bong Joo1, Nam Dong Kim1, Kwang Seop Jung2, and Jongheop Yi1, †
  • Department of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China
  • 1School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, 599 Gwanak-ro, Gwanak-gu, Seoul 151-744, Korea
  • 2GS Caltex Corporation, 104-4, Munji-dong, Yusung-gu, Daejeon 305-380, Korea
E-mail:
Mesoporous silica containing a ZrO2/SO4^(2-) superacid catalyst (SZS) was synthesized via a simple one-pot process. ZrO2/SO4^(2-) (SZ) was introduced during the synthesis of the SBA-15. When the molar ratio of Zr to Si was less than 0.37 : 1, a 2D-hexagonal pore structure was maintained. The superacidic SZ was successfully supported on mesoporous silica resulting in superacidity. The prepared SZS catalysts were applied to the conversion of glycerol to acrolein by dehydration and had considerable catalytic activity. The present study describes the first attempt to utilize mesoporous silica-supported superacid catalysts in the dehydration of glycerol to produce acrolein.
Keywords:Mesoporous Silica;ZrO2/SO4^(2-);One-pot Synthesis;Superacid;Acrolein
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