The photophysical and electroluminescent properties of blends of a polyfluorene derivative of the PPV type, poly[(9,9-dihexyl-9H-fluorene-2,7-diyl)-1,2-ethenediyl-1,4-phenylene-1,2 -ethenediyl] (labeled as LaPPS16) and poly(vinylcarbazole) - PVK are presented and discussed in terms of the operating light emission mechanisms. Static and dynamic fluorescence measurements and morphology data showed a powerful exciton migration from the host (PVK) to the guest (LaPPS16) resulting in emission coming from solely LaPPS16, even when in concentrations small as 1%. Electroluminescence was greatly enhanced with the blending; increases of 18 times in efficiency and 20 times in luminance were achieved in the blend containing 20% LaPPS16, with 3 V applied voltage. (C) 2009 Elsevier Ltd. All rights reserved.