화학공학소재연구정보센터
Industrial & Engineering Chemistry Research, Vol.33, No.12, 2989-2995, 1994
Oxidative Absorption of Hydrogen-Sulfide by a Solution of Ferric Nitrilotriacetic Acid Complex in a Cocurrent Down Flow Column Packed with Smv-4 Static Mixers
The reactive absorption of hydrogen sulfide into a solution of the ferric chelate of nitrilotriacetic acid (NTA) was studied at 13 degrees C in a cocurrent down flow column packed with stainless steel Sulzer SMV-4 static mixers. The concentration of ferric chelate varied from 200 to 30 mol/m(3); the pH ranged from 8.3 to 6.7. Volumetric liquid-phase mass transfer coefficients for H2S (k(L) alpha) could be measured and were correlated by k(L) alpha = 0.0572E(L)(0.55) for 0.060 less than or equal to U-L less than or equal to 0.156 [m/s], 0.59 less than or equal to U-G less than or equal to 2.95 [m/s], and 1.4 x 10(2) less than or equal to E(L) less than or equal to 3 X 10(3) [N/m(2)s], in which E(L) is the liquid energy dissipation factor and U-L and U-G are the superficial liquid and gas velocity, respectively. The k(L) alpha values observed with H2S under reactive conditions appeared to be approximately a factor of 4 higher than those observed for oxygen absorption in the same liquid over the same packing. The cause of the extra volumetric mass transfer obtained with H2S under similar conditions is not well understood yet. The reaction kinetics of hydrogen sulfide with the ferric chelate of NTA was found to be first order in both ferric NTA and H2S for 0.40 < p(A) < 0.8 kPa, 0 < C-Fe(III) < 200 mol/m(3), and 6.7 < pH < 8.2.