Kinetics of graft copolymerization of acrylamide and 2-hydroxyethylmethacrylate monomer mixture onto poly(ethylene terephthalate) fibers

Metin Arslan

Korean Journal of Chemical Engineering, Vol.27, No.3, 991-998, March, 2010

DOI10.1007/s11814-010-0125-7 Export Citation

Kinetics of graft copolymerization of acrylamide and 2-hydroxyethylmethacrylate monomer mixture onto poly(ethylene terephthalate) fibers

Metin Arslan^†

Faculty of Science and Art, Department of Chemistry, Cankiri Karatekin University, Cankiri 18100, Turkey

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Poly(ethylene terephthalate) (PET) fibers were grafted with acrylamide (AAm) and 2-hydroxyethylmethacrylate (HEMA) using benzoyl peroxide (Bz2O2) as initiator in aqueous media. PET fibers were swelled in dichloroethane (DCE) for 2 h at 90 ℃ to promote the incorporation and the subsequent polymerization of AAm/HEMA onto PET fibers. Variations of graft yield with time, temperature, initiator concentration and monomer mixture ratio were investigated. The optimum initiator concentration was found to be 10 mmol/L. The maximum graft yield was obtained (prep.) 273%. The optimum temperature and polymerization time were found to be 85 ℃ and 120 min, respectively. The rate of grafting was found to be proportional of the 1.39 and 0.37 powers of AAm/HEMA and Bz2O2 concentrations, respectively. The grafted PET fibers were characterized by FTIR spectroscopy and scanning electron microscopy (SEM). Further changes in properties of grafted PET fibers such as water absorption capacity and diameter were determined. The dyeability of the PET fibers increased with an increase in grafting with acidic and basic dyes.

Keywords:Poly(Ethylene Terephthalate) Fibers;2-Hydroxyethylmethacrylate;Acrylamide;Graft Copolymerization;Monomer Mixture

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[1] Education Department, Man-made Fiber Producers Association, Inc., Man-made Fiber Fact Book (1978)

[2] Sakurada I, Ikada Y, Kawahara T, J. Polym. Sci. A., 11, 2329 (1973)

[3] Buxbaum LH, Angew. Chem., 80, 225 (1968)

[4] Hiller KW, Homopolymer, Man-made fibers Sci and Technol, Interscience, John Wiley and Sons, New York (1968)

[5] Kubota H, Fukushima Y, Kuwabara S, Eur. Polym., 33, 61 (1997)

[6] Uchida E, Uyama Y, Ikada Y, Text. Res. J., 61, 483 (1991)

[7] Mares E, Arther JC, Harris JA, Text. Res. J., 46, 983 (1976)

[8] El Salmawi K, El Naggar AM, Attia SE, Polym. Int., 44, 181 (1997)

[9] Gupta KC, Khandekar K, J. Macromol. Sci., 40(2), 155 (2003)

[10] Coskun R, Sacak M, Karakisla M, J. Appl. Polym. Sci., 97(5), 1795 (2005)

[11] Coskun R, Eur. Polym. J., 43, 1428 (2007)

[12] Celik M, Sacak M, J. Appl. Polym. Sci., 38, 539 (1996)

[13] Coskun R, React. Funct. Polym., 68, 1704 (2008)

[14] Sacak M, Pulat E, J. Appl. Polym. Sci., 38, 539 (1989)

[15] Abdel Bary EM, Sarhan AA, Abdel Razlk HH, J. Appl.Polym. Sci., 35, 439 (1988)

[16] Campbell D, Araki K, Turner T, J. Polym. Sci. A., 19, 461 (1966)

[17] Campbell D, Turner T, J. Polym. Sci. A., 5, 2199 (1967)

[18] Campbell D, Monteith LK, Turner T, J. Polym. Sci. Part A-1, 8, 2703 (1970)

[19] Arslan M, Yigitoglu M, Sanli O, Unal HI, Polym. Bull., 51(3), 237 (2003)

[20] Sacak M, Bastug N, Talu M, J. Appl. Polym. Sci., 50, 1123 (1993)