화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.16, No.2, 220-223, March, 2010
DOI10.1016/j.jiec.2009.08.009  Export Citation
Ligandless palladium supported on SiO2-TiO2 as effective catalyst for Suzuki reaction
Guozhi Fan†, Bing Zou, Siqing Cheng, and Lihui Zheng
  • School of Chemical and Environmental Engineering, Wuhan Polytechnic University, Wuhan 430023, China
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TiO2-SiO2 mixed oxides were prepared by the homogeneous precipitation method, and the supports were characterized by XRD, IR and BET. Ligandless palladium supported on SiO2-TiO2 was prepared by the deposition-precipitation method and used as recoverable catalyst for Suzuki reactions. The results revealed that the supported catalyst Pd/SiO2-TiO2 exhibited excellent catalytic activity for the coupling of aryl bromides with arylboronic acid, and also exhibitedmoderate catalytic activity for the coupling of aryl chlorides. The catalyst was recycled by simple filtration and reused without further disposal, no significant Pd leaching and loss of catalytic activity was observed except the first reuse.
Keywords:Ligandless Pd;Suzuki reaction;Supported catalyst;SiO2-TiO2
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