A hydrogen molecule entrapped in the cages of icy hydrogen hydrate is confined in host water framework and thus behaves unlike pure solid or liquid hydrogen. The gamma-irradiated hydrogen radicals are for the first time observed from ESR and solid-state MAS H-1 NMR spectra to stably exist in the icy hydrate channels without any collapse of the host framework, confirming the chemical shift consistency of ionized hydrogen derivatives. We discuss we confined icy hydrate channels, which can act as potential storage sites for simultaneously imprisoning both molecular and ionized hydrogen and further as icy nanoreactors.