화학공학소재연구정보센터
Journal of Power Sources, Vol.195, No.9, 2564-2569, 2010
New design of electric double layer capacitors with aqueous LiOH electrolyte as alternative to capacitor with KOH solution
Activated carbon (AC) fiber cloths and a hydrophobic microporous polypropylene (PP) membrane, both modified with lithiated acetone oligomers, were used as electrodes and a separator in electric double layer capacitors (EDLCs) with aqueous lithium hydroxide (LiOH) as the electrolyte. Electrochemical characteristics of EDLCs were investigated by cyclic voltammetry (CV), galvanostatic charge-discharge cycle tests and impedance spectroscopy (EIS), compared with a case of the capacitor with aqueous potassium hydroxide (KOH) as an electrolyte. As a result, the capacitor with LiOH aqueous solution and a modified separator and electrodes was found to exhibit higher specific capacitance, maximum energy stored and aximum power than that with KOH aqueous solution. (C) 2009 Elsevier B.V. All rights reserved.