화학공학소재연구정보센터
Journal of Power Sources, Vol.195, No.7, 1854-1858, 2010
La1-xSrxCoO3 (x=0.1-0.5) as the cathode catalyst for a direct borohydride fuel cell
Direct borohydride fuel cells (DBFCs), with a series of perovskite-type oxides La1-xSrxCoO3 (x=0.1-0.5) as the cathode catalysts and a hydrogen storage alloy as the anode catalyst, are studied in this paper. The structures of the perovskite-type catalysts are mainly La1-xSrxCoO3 ((x) = 0.1-0.5) oxides phases. However, with the increase of strontium content, the intensities of the X-ray diffraction peaks of the impure phases La2Sr2O5 and SrLaCoO4 are gradually enhanced. Without using any precious metals or expensive ion exchange membranes, a maximum current density of 275 mA cm(-2) and a power density of log mWcm(-2) are obtained with the Sr content of x = 0.2 at 60 degrees C for this novel type of fuel cell. (C) 2009 Elsevier B.V. All rights reserved.