화학공학소재연구정보센터
Journal of Power Sources, Vol.190, No.1, 162-172, 2009
Heat tolerance of automotive lead-acid batteries
Starter batteries have to withstand a quite large temperature range. In Europe, the battery temperature can be -30 degrees C in winter and may even exceed +60 degrees C in summer. In most modern cars, there is not much space left in the engine compartment to install the battery. So the mean battery temperature may be higher than it was some decades ago. In some car models, the battery is located in the passenger or luggage compartment, where ambient temperatures are more moderate. Temperature effects are discussed in detail. The consequences of high heat impact into the lead-acid battery may vary for different battery technologies: While grid corrosion is often a dominant factor for flooded lead-acid batteries, water loss may be an additional influence factor for valve-regulated lead-acid batteries. A model was set up that considers external and internal parameters to estimate the water loss of AGM batteries. Even under hot climate conditions, AGM batteries were found to be highly durable and superior to flooded batteries in many cases. Considering the real battery temperature for adjustment of charging voltage, negative effects can be reduced. Especially in micro-hybrid applications, AGM batteries cope with additional requirements much better than flooded batteries, and show less sensitivity to high temperatures than suspected sometimes. (C) 2009 Elsevier B.V. All rights reserved.