A series of barium aluminosilicate glasses modified with CaO and B2O3 were prepared and evaluated with respect to their suitability in sealing planar solid oxide fuel cells (SOFCs). At a target operating temperature of 750 degrees C, the long-term coefficient of thermal expansion (CTE) of one particular composition (35 mol% BaO, 15 mol% CaO, 10 mol% B2O3, 5 mol% Al2O3, and bal. SiO2) was found to be particularly stable, due to devitrification to a mixture of glass and ceramic phases. This sealant composition exhibits minimal chemical interaction with the yttria-stabilized zirconia electrolyte, yet forms a strong bond with this material. Interactions with metal components were found to be more extensive and depended on the composition of the metal oxide scale that formed during sealing. Generally alumina-scale formers exhibited a more compact reaction zone with the glass than chromia-scale forming alloys. Mechanical measurements conducted on the bulk glass-ceramic and on seals formed using these materials indicate that the sealant is anticipated to display adequate long-term strength for most conventional stationary SOFC applications. (C) 2008 Elsevier B.V. All rights reserved.