Three different synthesis techniques (hydrothermal synthesis, modified Pechini synthesis and Pechim synthesis) were successfully used for preparation of Li2FeSiO4 samples. The obtained samples possess some differences in the morphology and in the particle size, as well as in the presence of in situ formed carbon. The best electrochemical performance has been obtained with the smallest particles embedded into carbon matrix. Such a Li2FeSiO4/C composite contains the highest amounts of impurities (Fe2O3, SiO2 and Li2SiO3) and only 68.8 at.% of iron is in the form of Fen as detected by Mossbauer spectroscopy, respectively. Despite the highest amount of impurities, the sample shows the highest reversible capacity (approximately 100 mAh g(-1) based on whole silicate-derived material). With the proper structuring of Li2FeSiO4/C composites, utilisation of large part of capacity is also possible at current densities corresponding to C/5 and C/2 cycling rate. A lower amount of impurities was found in the samples that do not contain any in situ carbon after synthesis. Among them, the highest purity is possessed by the sample prepared at 900 degrees C, as determined using Mossbauer spectroscopy. The results obtained by Mossbauer spectroscopy and XRD analysis indicate on the differences in the crystal structure between the thermally treated samples and the sample prepared by hydrothermal synthesis. (c) 2007 Elsevier B.V. All rights reserved.