Journal of Polymer Science Part A: Polymer Chemistry, Vol.46, No.19, 6489-6495, 2008
Preparation of flexible and transparent polylactic acids films by crystallization manipulation
Highly flexible and transparent polylactic acids (PLAs) films were successfully prepared by manipulating their crystallization. The semicrystalline poly(L-lactic acid) V was blended with a noncrystalline poly(DL-lactic acid) (DL) together with diglycerol tetraacetate (DGTA). Optimal DGTA content to plasticize PLAs was about 17%. Addition of DL hindered the crystallization of the films. Tensile strengths of the films having DL content more than 5% were about 10 MPa while the elongations at break were boosted as DL content increased. Films having L/DL ratio of 50/50 showed elongations at break of 270%. Stretch ability and clarity of films containing 15-50% DL were fair although they were subjected to annealing at 60 degrees C for 1 h. (C) 2008 Wiley Periodicals, Inc.