The homogeneous ruthenium complex [(RuCl2)-Cl-II(bpea)(PPh3)], where bpea = N,N-bis-(2-pyridylmethyl)ethylamine, has been immobilised on an amorphous AlPO4 support through phosphamide bonds that are comparatively more stable than organosilane bonds, The catalyst was characterised by means of UV-vis and DRIFT and its activity was compared to that of the homogeneous complex in the liquid-phase hydrogenation of a range of alkenes. The heterogenized catalyst exhibited very good activities and excellent reusabilities (Up to 25 runs) in the hydrogenation reaction. (C) 2009 Elsevier B.V. All rights reserved.