Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) hollow fibers were fabricated using a phase inversion/sintering method. As oxygen permeation of BSCF hollow fibers is controlled by the rate surface exchange kinetics, catalytic Ag particles were coated on both inner and outer surfaces using chemical deposition method, as verified by SEM and EDX The Ag coated BSCF membranes showed up to 100% increase in oxygen permeation at 700 degrees C, and improvements lower than 10% were measured at 950 degrees C as compared with unmodified membranes. It was found that Ag catalyst surface loading was non-homogenous and concentrated on the perovskite grain boundaries. As a result, lighter Ag surface loading delivered improved oxygen flux while oxygen flux reached a maximum even though in the presence of excess catalyst loading. The catalytic activity of Ag was beneficial in enhancing surface reaction kinetics up to 850 degrees C attributed to the spillover effect. Above this temperature, the increase in oxygen permeation rate was marginally diminished due to the reduction of the spillover effect. (C) 2009 Elsevier B.V. All rights reserved.