Microporous poly(vinylidene fluoride)/polyethylene oxide-co-polypropylene oxide-co-polyethylene oxide (PVDF/PEO-PPO-PEO, or PVDF/F127) blend membranes were prepared via thermally induced phase separation (TIPS) process using sulfolane as the diluent. Then they were soaked in a liquid electrolyte to form polymer electrolytes. The effects of F127 weight fraction on the morphology, crystallinity and porosity of the blend membranes were studied. It was found that both electrolyte uptake of blend membranes and ionic conductivity of corresponding polymer electrolytes increased with the increase of F127 weight fraction. The maximum ionic conductivity was found to reach 2.94 +/- 0.02 x 10(-3) S/cm at 20 degrees C. Electrochemical stability window was stable up to 4.7 V (vs. Li+/Li). The testing results indicated that the PVDFIF127 blend membranes prepared via TIPS process can be used as the polymer microporous matrices of polymer electrolytes for lithium ion batteries. (C) 2008 Elsevier B.V. All rights reserved.