The purpose of this study is to assess the composition of wet precipitation in three sites of the metropolitan area of Porto Alegre. Besides the variables usually considered, such as pH, conductivity, major ions (Cl-. NO3-, F-, SO42-, Na+, K+, Mg2+, NH4+ and Ca2+) and metallic elements (Cd, Co, Cr, Cu, Fe. Mn and Ni), the suspended matter was examined by X-ray diffraction (XRD) and scanning electron microscopy (SEM), with energy dispersive system (EDS), for better identification of possible anthropogenic material in this wet precipitation. Results showed an alkaline pH in the samples analyzed and higher concentrations for Na+, Cl- and SO42-. The acidification and neutralization potential between anions (SO42- + NO3-) and cations (Ca2+ + Mg2+ + K+ + NH4+) showed a good correlation (0.922). The metallic elements with highest values were Zn, Fe and Mn. Results of XRD identified the presence of some minerals such as quartz, feldspar, mica, clay, carbonates and sulfates. In samples analyzed with SEM, we detected pyroxene, biotite, amphibole and oxides. Cluster analysis (CA) was applied to the data matrix to identify potential pollution sources of metals (natural or anthropogenic) and the association with minerals found in the analysis of SEM. (C) 2009 Elsevier B.V. All rights reserved.