화학공학소재연구정보센터
Journal of Hazardous Materials, Vol.161, No.1, 270-275, 2009
Identifying the potential sources of di-(2-ethylhexyl) phthalate contamination in the sediment of the Houjing River in southern Taiwan
Sediment samples were analyzed for di-(2-ethylhexyl) phthalate (DEHP), an organic endocrine disruptor, in Houjing River in southern Taiwan. The average DEHP concentration at 10 sampling locations, spanning from upper, middle. and lower segments of the stream, was calculated at 3.81 +/- 6.36 mg kg(-1) dry wt. Highest concentration was recorded at the Jhongsing Bridge (20.22 mg kg(-1) dry wt.) near the Dashe Industrial Park, followed by the Renwu Bridge (8.93 mg kg(-1) dry wt.) near the Renwu Industrial Park. The surface sediment concentration of DEHP was found to be higher in the dry season (October and December), and lower in the wet (flood) season (August), indicating that sources of DEHP remained active and continued to recharge the Houjing River. Vertical sediment core analysis revealed that highest concentration occurred at the depth of 40-60 cm, indicating that historical discharges of DEPH may have been higher than recent years. Domestic comparison of DEHP concentrations in sediment from highest to lowest could be categorized as northern, southern, central, and eastern Taiwan, respectively, and seemed to be positively correlated with population density and/or industrial activity. Compared to other countries, DEHP concentration of the Houjing River was relatively higher than rivers studied in Japan, Germany, Italy, and Malaysia, and was relatively lower than the Aire and Trent Rivers in the United Kingdom. (C) 2008 Elsevier B.V. All rights reserved.