A very simple and powerful microextraction procedure, the dispersive liquid-liquid microextraction (DUME). was used for the determination of the content of 10 polychlorinated biphenyls (PCBs) in water samples. using gas chromatography coupled with electron-capture detection (GC-ECD). The appropriate amount of acetone (disperser solvent) and chlorohenzene (extraction solvent) at the microlevel volume was used for (his procedure. The conditions for the microextraction performance were investigated and optimized. The optimized method exhibited a good linearity (R-2 >0.996) over the Studied range (0.005-2 mu g L-1). illustrating a satisfactory precision level with R.S.D. values between 4.1% and 11.0%. The values of the detection limit (S/N=3) were found to be lower than 0.002 mu g L-1. Furthermore, a large enrichment factor for the analytes (up to a 540-fold) was achieved in a very short time for only a 5.00-mL water sample. The effectiveness of the method towards real samples was tested by analyzing well, river and seawater samples. The relative recoveries of the well, river and seawater samples, which had been spiked with different levels of PCBs were equal to 92.0-114.0%. 97.0-102.0% and 96.0-103.0%, respectively. The attained results demonstrated that DLLME combined with GC-ECD was a fast and inexpensive technique for the PCBs determination in water samples. (C) 2008 Elsevier B.V. All rights reserved.