In this study, a large amount of toxic and reactive fluorine (F2) was produced in the atmospheric-pressure microwave discharge environment by adding additives to abate sulfur hexafluoride (SF6). When H2,was added, the selectivity of F2 was as high as 89.7% at inlet H2/SF6 molar ratio (RH,) = 1. Moreover, the conversion of SF6 significantly increased from 33.7% (without additive) to 97.7% (RH2 = 5) at [SF 61 = I%, and 0.8 kW because the addition of H, inhibited the recombination of SF6. With the addition Of 02, H2 + 02 or H20, the selectivity of F2 was still greater than 81.2%, though toxic byproducts, including S02172, SOF2, SOF4, S02, NO, and HF, were detected. From optical emission spectra, SF, was identified. revealing the SF6 dissociation process might be carried out rapidly through an electron impaction reaction: SF6 --). SF2 + 4F. Subsequently, F, was formed via the recombination of F atoms. (c) 2008 Elsevier BX All rights reserved.