Journal of Crystal Growth, Vol.311, No.21, 4549-4552, 2009
Float zone growth of Dy:GdVO4 single crystals for potential use in solid-state yellow lasers
Single crystals of dysprosium-doped gadolinium orthovanadate (Dy:GdVO4) were successfully grown by the floating zone method and their fluorescence properties were investigated. The as-grown crystals did not contain any macroscopic defects such as cracks and inclusions for any Dy-concentration of up to 4 at%. Every crystal showed optical homogeneity under observation with a polarizing microscope; that is, no low-angle grain boundaries and growth striations were detected. In the visible region two distinct, fluorescence bands were observed around 480 and 575 nm, corresponding to F-4(9/2) -> H-6(15/2) and 4F(9/2) -> H-6(13/2) transitions, respectively. The excitation spectrum for the emission of 573 nm indicates the possibility to use a commercially available laser diode of 450 nm as a pumping source for solid-state yellow laser. (C) 2009 Elsevier B.V. All rights reserved.