This paper discussed the coagulation characteristics of BPA with polyaluminum chloride (PACl-Al-13) as coagulant, examined the impact of coagulation pH, PACl-Al-13 dosage. TOC (total organic carbon) and turbidity on BPA removal, and analyzed the possible dominant mechanisms in water coagulation process. Formation and performance of flocs during coagulation processes were monitored using photometric dispersion analyzer (PDA). When the concentration of humic acid matters and turbidity was low in the solution, the experimental results showed that the removal of BPA experienced increase and subsequently decrease with the PACl-Al-13 dosage increasing. The optimal PACl-Al-13 dosage was found at BPA/PACl-Al-13= 1:2.6(M/M) under our experiment conditions. Results show that the maximum BPA removal efficiency occurred at pH 9.0 due to the adsorption by Al-13 aggregates onto BPA rather than charge neutralization mechanism by polynuclear aluminous salts in the solution. The humic acid matters and kaolin in the solution have significant effect on BPA removal with PACl-Al-13 in the coagulation. The BPA removal will be weakened at high humic matters. The removal rate of BPA increased and subsequently decreased with the turbidity increasing. (C) 2009 Elsevier Inc. All rights reserved.