화학공학소재연구정보센터
Journal of Chemical Thermodynamics, Vol.40, No.6, 1038-1039, 2008
On the definition of the excess permittivity of a fluid mixture
It is shown that under the assumption of no intermolecular interaction, the permittivity of a homogeneous linear and isotropic fluid mixture is the sum of the individual permittivities weighted with the mole fractions of the components. For definiteness, a proof is given for gasses under standard temperature and pressure; it is, however, easy to generalize it to other conditions, as well as to liquids, as long as the assumption of no intermolecular interaction is retained. Also, although the proof is given for a binary mixture, it is a simple exercise to extend it to any multicomponent mixture. (C) 2008 Elsevier Ltd. All rights reserved.