An assessment of the potential availability of selected residues from maize, cassava, millet, plantain, groundnuts, sorghum, oil palm, palm kernel, and cowpeas for possible conversion to renewable energy in Nigeria has been made. It is estimated that nearly 58 million tonnes of these residues were potentially available in the year 2004 with energy potential of about 20.8 million tonnes oil equivalents. The residue availability for 2010 is projected to be about 80 million tonnes. These residues, when converted to energetically usable forms, can substitute or complement the fossil energy sources in Nigeria by more than 80%.