Experiments were carried out in a multipath air inlet one-dimensional furnace to assess NO., emission characteristics of the staged combustion of anthracite coal. These experiments allowed us to study the impact of pulverized coal fineness and burnout air position on emission under both deep and shallow air-staged combustion conditions. We also studied the impact of char-nitrogen release on both the burning-out process of the pulverized coal and the corresponding carbon content in fly ash, We found that air-staged combustion affects a pronounced reduction in NO., emissions from the combustion of anthracite coal. The more the air is staged, the more NO., emission is reduced. In shallow air-staged combustion (f(M) = 0.85), the fineness of the pulverized coal strongly influences emissions, and finer coals result in lower emissions. Meanwhile, the burnout air position has only a weak effect. In the deep air-staged combustion (f(M) = 0.6), the effect of coal fineness is smaller, and the burnout air position has a stronger effect. When the primary combustion air is stable, NOx, emissions increase with increasing burnout air. This proves that, in the burnout zone, coal char is responsible for the discharge of fuel-nitrogen that is oxidized to NOx. The measurement of secondary air staging in a burnout zone can help inhibit the oxidization of NO caused by nitrogen release. Air-staged combustion has little effect on the burnout of anthracite coal, which proves to be suitable for air-staged combustion.