Tightly constrained determinative methods can be used to characterise the silica minerals (opal-A, opal-CT, opal-C, quartz, moganite) and physical properties of silica sinters. Optimal X-ray powder diffraction operating parameters indicate silica lattice order/disorder using untreated. dry, < 106 mu m powders scanned at 0.6 degrees 2 theta/min with a step size of 0.01 degrees from 10-40 degrees 2 theta and an internal Si standard. Simultaneous differential thermal and thermogravimetric analysis of 15.0 +/- 0.1 mg sinter samples of < 106 mu m grain size, at a heating rate of 2 theta degrees C/min in dry air, identify thermal events associated with dehydration, organic combustion, and changes of state. Where abundant organic matter is present, nitrogen is the preferred atmosphere for thermal analysis. Thermogravimetric-determined water contents of sinters differ from Penfield determinations reflecting the differing nature of the two techniques. Laser Raman microprobe techniques can be used to explore the mineralogy of particular sinter morphologies and habits down to 10 mu m diameter. The nature of the silica species present can assist in characterising individual sinter deposits and, combined with textural, density and/or porosity determinations, can lead to a better understanding of the hydrology and paleohydrology of a geothermal prospect. (C) 2000 CNR.