A thin-film photoelectrocatalytic (PEC) reactor with slant-placed TiO2/Ti anode was developed and successfully applied to degrade Rhodamine B (RhB) and textile effluent. Using a 5-150 mg L-1 RhB solution as the model system, thin-film PEC removed total color and TOC by 99-28% and 78-15%, respectively, in 1 h, which is much higher than 82-7% and 60% to zero by conventional PEC. The enhanced treatment efficiency achieved by thin-film PEC process was attributed to the significantly reduced path length of irradiation light source. The wastewater was kept circulating during the experiments to timely refresh the aqueous film on the TiO2/Ti anode and promote the mass transfer of the target pollutants and the degradation products in the bulk solution. The thin-film PEC reactor can degrade both simulated and real dye wastewater efficiently under UV light irradiation. Results suggested that thin-film PEC was particularly superior for treating a high concentration solution. The thin-film PEC reactor was also applied to treat RhB solution efficiently under solar light irradiation. The recycle experiments demonstrated excellent stability and reliability of the slant-placed TiO2/Ti anode. This study proposed a simple and effective method to design PEC reactor applicable for industrial dye wastewater treatment. (C) 2009 Elsevier B.V. All rights reserved.