Korean Journal of Chemical Engineering, Vol.27, No.1, 241-248, January, 2010
Adsorption of carbon dioxide onto PDA-CP-MS41 adsorbent
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Carbon dioxide was adsorbed onto mesoporous adsorbent of PDA-CP-MS41, which was synthesized by CP-MS41 with propylene diamine, in a laboratory-scale packed-bed. Experiments were carried out at different adsorption temperatures (30-60 ℃), amounts of adsorbent (1-3 g), and flow rates of nitrogen (15-60 cm3/min) to obtain the breakthrough curves of CO2. These curves were tested by the deactivation model, which combined the adsorption of CO2 and the deactivation of adsorbent particles. The adsorption rate constant and the deactivation rate constant were evaluated through analysis of the experimental breakthrough data using a nonlinear least squares technique. The experimental breakthrough data were fitted very well to the deactivation model than the adsorption isotherm models in the literature.
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