This study provides insight into the effect of Pt dispersion on the overall rate and product distribution during NOx storage and reduction. The storage and reduction performance of Pt/BaO/A(2)O(3) monoliths with varied Pt dispersion (3%, 8%, and 50%) and fixed Pt (2.48 wt.%) and BaO (13.0 wt.%) loadings is reported. At low temperature (<200 degrees C) the differences in storage and reduction activity were the largest between the three catalysts. The amount of NOx stored increased with increased dispersion, as did the amount of stored NOx that was reduced. These trends are attributed to larger Pt surface area and Pt-BaO interfacial perimeter, the latter of which enhances the spillover of surface species between the precious metal and storage components. At high temperature (370 degrees C), the stored NOx was almost completely regenerated for the three catalysts. However, the regeneration of the 3% dispersion catalyst was much slower, suggesting a rate limitation involving the reverse spillover of stored NOx to Pt and/or of adsorbed hydrogen from Pt to BaCl. The results indicate that the catalyst dispersion and operating conditions may be tuned to achieve the desired ammonia selectivity. For the aerobic regeneration feed, the most (net) NH3 was generated by the 50% dispersion catalyst at the lowest temperature (125 degrees C), by the 3% dispersion catalyst at the highest temperature (340 degrees C) and by the 8% dispersion catalyst at the intermediate temperatures (170-290 degrees C). Similar trends were observed for the net production of NH3 with an anaerobic regeneration feed. A phenomenological picture is proposed that describes the effects of Pt dispersion consistent with the established spatio-temporal behavior of the lean NOx trap. (C) 2009 Elsevier B.V. All rights reserved.