Snapshot proper orthogonal decomposition (POD) technique has been applied to reveal the dominant flow structures, their dynamics and length scales in six widely used industrial equipments (stirred tank, bubble column, Taylor-Couette flow (annual contactor), ultrasonic reactor, jet reactor, and channel flow). The variation in length scale of structures within an equipment, with change in its operating conditions (Reynolds number and power input) or change in its geometric configuration (sparger and impeller designs), has been brought out in this work. The planar data set for POD analysis was obtained from particle image velocimetry (PIV) and large eddy simulation (LES) studies. The dominant spatial topology was analyzed by using the velocity and vorticity POD modes. The modes have revealed the following flow structures: the ascending streaks and bursts in channel flow, the vortex tube and leading edge vortices in jets, the irregular small chaotic vortices in Taylor-Couette flow, the variation in plume oscillation and flow structures in the vortical region of bubble column resulting from changes in sparger design, the high intensity vortices near the source of ultrasound in the ultrasonic reactor and the effect of impeller designs on dominant flow structures and near blade vortices in the stirred tank. The length scales of structures are obtained by applying image processing on the spatial modes. The dynamics of these flow structures in each of the items of equipment is captured by reconstructing the flow field using appropriate spatial and temporal modes that contribute to these structures. Further, a unique attempt has been made to correlate the length scale distribution with the mixing time. (c) 2008 Elsevier Ltd. All rights reserved.