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Advanced Functional Materials, Vol.18, No.16, 2444-2454, 2008
Self-assembly of DNA-templated polypyrrole nanowires: Spontaneous formation of conductive nanoropes
Polypyrrole nanowires formed by polymerization of pyrrole on a DNA template self-assemble into rope-like structures. These 'nanoropes' may be quite smooth (diameters 5-30 nm) or may show frayed ends where individual strands are visible. A combination of electric force microscopy, conductive atomic force microscopy and two-terminal current-voltage measurements show that they are conductive. Nanoropes adhere more weakly to hydrophobic surfaces prepared by silanization of SiO2 than to the clean oxide; this effect can be used to aid the combing of the nanoropes across inicroelectrode devices for electrical characterization.