Comparison of gamma ray and electron beam irradiations on the degradation of carboxymethylcellulose

Jong-il Choi; Jae-Hun Kim; Kwang-Won Lee; Beom-Suk Song; Yohan Yoon; Myung-Woo Byun; Ju-Woon Lee

Korean Journal of Chemical Engineering, Vol.26, No.6, 1825-1828, November, 2009

DOI10.1007/s11814-009-0279-3 Export Citation

Comparison of gamma ray and electron beam irradiations on the degradation of carboxymethylcellulose

Jong-il Choi, Jae-Hun Kim, Kwang-Won Lee¹, Beom-Suk Song, Yohan Yoon, Myung-Woo Byun, and Ju-Woon Lee^†

Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, Jeongeup 580-185, Korea
¹Department of Orthopaedic Surgery, Eulji University School of Medicine, Daejeon 302-799 Korea

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Carboxymethylcellulose (CMC) is used for a variety of applications due to its superior properties of high viscosity at a low concentration. In this study, the difference between a gamma ray (GR) irradiation from Co-60 and an electron beam (EB) irradiation with 10 MeV Energy on the viscosity change in CMC solution was compared. At the same irradiation doses, the viscosity of the CMC solution was more severely decreased by GR. Electron spin resonance spectroscopy revealed that the radicals in the CMC were more generated by GR, but there was no difference in the Fourier transform infrared spectra of both irradiated CMC solutions. Also, the degree of substitution in CMC was not changed by both irradiation events. From these results, it can be concluded that EB irradiation could better minimize the decrease in the viscosity of the solution with CMC for the sterilization than GR.

Keywords:Carboxymethylcellulose;Gamma Ray;Electron Beam;Viscosity;Electron Spin Resonance

[References]

Sanford PA, Baird J, Industrial utilization of polysaccharides in: The polysaccharides, Ed. Aspinall GA, Academic Press, New York, 411 (1983)
Yang XH, Zhu WL, Cellulose, 14, 409 (2007)
Santa-Comba A, Pereira A, Lemos R, Santos D, Amarante J, Pinto M, J. Bio. Mater. Res., 55, 396 (2001)
von Sonntag C, Radiat. Phys. Chem., 67, 353 (2003)
Fei I, Wach RA, Mitomo H, Yoshii F, Kume T, J. Appl. Polym. Sci., 78(2), 278 (2000)
Liu P, Zhai M, Li J, Peng J, Wu J, Phys. Chem., 63, 525 (2002)
Abramyan EA, Industrial electron accelerators and applications, Springer-Verlag, Berlin (1999)
Wach RA, Mitomo H, Yoshii F, Kume T, J. Appl. Polym. Sci., 81(12), 3030 (2001)
Capitani D, Porro F, Segre AL, Carbohyd. Res., 42, 283 (2000)
Ershov BG, Russian Chemical Reviews, 67, 315 (1998)
Wach RA, Mitomo H, Nagasawa N, Yoshii F, Radiat. Phys. Chem., 68, 771 (2003)
Ikada Y, Nakamura K, Ogata S, Makino K, Tajima K, Endoh N, Hayashi T, Fujita S, Fujisawa A, Masuda S, Oonish H, J. Polym. Sci., 37, 159 (2000)
Franco AP, Merce ALR, React. Funct. Polym., 66, 667 (2006)

[Referenced By]

[1] Sanford PA, Baird J, Industrial utilization of polysaccharides in: The polysaccharides, Ed. Aspinall GA, Academic Press, New York, 411 (1983)

[2] Yang XH, Zhu WL, Cellulose, 14, 409 (2007)

[3] Santa-Comba A, Pereira A, Lemos R, Santos D, Amarante J, Pinto M, J. Bio. Mater. Res., 55, 396 (2001)

[4] von Sonntag C, Radiat. Phys. Chem., 67, 353 (2003)

[5] Fei I, Wach RA, Mitomo H, Yoshii F, Kume T, J. Appl. Polym. Sci., 78(2), 278 (2000)

[6] Liu P, Zhai M, Li J, Peng J, Wu J, Phys. Chem., 63, 525 (2002)

[7] Abramyan EA, Industrial electron accelerators and applications, Springer-Verlag, Berlin (1999)

[8] Wach RA, Mitomo H, Yoshii F, Kume T, J. Appl. Polym. Sci., 81(12), 3030 (2001)

[9] Capitani D, Porro F, Segre AL, Carbohyd. Res., 42, 283 (2000)

[10] Ershov BG, Russian Chemical Reviews, 67, 315 (1998)

[11] Wach RA, Mitomo H, Nagasawa N, Yoshii F, Radiat. Phys. Chem., 68, 771 (2003)

[12] Ikada Y, Nakamura K, Ogata S, Makino K, Tajima K, Endoh N, Hayashi T, Fujita S, Fujisawa A, Masuda S, Oonish H, J. Polym. Sci., 37, 159 (2000)

[13] Franco AP, Merce ALR, React. Funct. Polym., 66, 667 (2006)