Preparation of molecularly imprinted polymer membrane with blending trimethoprim-MIP and polysulfone and its transport properties

Peimin Fan; Bing Wang

Korean Journal of Chemical Engineering, Vol.26, No.6, 1813-1820, November, 2009

DOI10.1007/s11814-009-0256-x Export Citation

Preparation of molecularly imprinted polymer membrane with blending trimethoprim-MIP and polysulfone and its transport properties

Peimin Fan, and Bing Wang^†

Key Laboratory of Hollow Fiber Membrane Materials and Membrane Process of the Ministry of Education,School of Materials Science and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300160, China

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An imprinted polymer membrane (IPM) with blending trimethoprim-MIP and polysulfone (PSF) was prepared by bulk polymerization and membrane preparation. In the process of the preparation, the influencing factors on membrane structure and properties, such as the concentration of PSF, the content of additive polyethelene glycol (PEG) and TMP imprinted polymer, were thoroughly investigated by scanning electron microscopy (SEM) and the membrane performance tester. The adsorption properties and selectivity properties of IPM to different substrates were estimated by using the method of equilibrium binding experiments. Finally, the transport properties of the membranes were investigated by using the diffusion chambers. The results showed that the imprinted polymer membrane exhibited a high selectivity for TMP.

Keywords:Imprinted Polymer Membrane;Molecularly Imprinted Polymer;High Selectivity;SEM;Transport Properties

[References]

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Wulff G, Sarhan A, Zabrocki K, Tetrahedron Lett., 44, 4329 (1973)
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Ramamoorthy M, Ulbricht M, J. Membr. Sci., 217(1-2), 207 (2003)
Malaisamy R, Ulbricht M, Sep. Purif. Technol., 39(3), 211 (2004)
Kondo Y, Yoshikawa M, Analyst, 126, 871 (2001)
Marx-Tibbon S, Willner I, J. Chem. Soc., Chem. Commun., 10, 1261 (1994)
Mathewkrotz J, Shea KJ, J. Am. Chem. Soc., 118(34), 8154 (1996)
Yang Z, Xu Z, Bing N, Chem. Ind. Eng. Prog., 25, 131 (2006)
He X, He G, Zeng B, Sun H, Yang H, Chen S, Zhou H, Journal of Xiamen University (Natural Science), 40, 495 (2001)
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Zhou J, He X, Yang W, Shi H, Chemical Journal of Chinese Universities, 19, 1388 (1998)
Hawkins DM, Trache A, Ellis EA, Stevenson D, Holzenburg A, Meininger GA, Reddy SM, Biomacromolecules, 7(9), 2560 (2006)
Jin Y, Row KH, Korean J. Chem. Eng., 22(2), 264 (2005)
Ferrer I, Lanza F, Tolokan A, Horvath V, Sellergren B, Horvai G, Barcelo D, Anal. Chem., 72, 3934 (2000)
Stevenson D, Trends in Ana1ytical Chemistry, 18, 154 (1999)

[Referenced By]

[1] Ye L, Ramstrom O, Mosbach K, Anal. Chem., 70, 2789 (1998)

[2] Jin Y, Choi DK, Row KH, Korean J. Chem. Eng., 25(4), 816 (2008)

[3] Percival CJ, Stanley S, Galle M, Braithwaite A, Newton MI, McHale G, Hayes W, Anal. Chem., 73, 4225 (2001)

[4] Liu Q, Zhou Y, Liu Y, Chin. J. Anal. Chem., 27, 1341 (1999)

[5] Wulff G, Sarhan A, Zabrocki K, Tetrahedron Lett., 44, 4329 (1973)

[6] Yoshikawa M, Izumi J, Kitao T, React. Funct. Polym., 42(1), 93 (1999)

[7] Yoshikawa M, Izumi J, Guiver MD, Robertson GP, Macromol. Mater. Eng., 286, 52 (2001)

[8] Wang HY, Kobayashi T, Fukaya T, Fujii N, Langmuir, 13(20), 5396 (1997)

[9] Ramamoorthy M, Ulbricht M, J. Membr. Sci., 217(1-2), 207 (2003)

[10] Malaisamy R, Ulbricht M, Sep. Purif. Technol., 39(3), 211 (2004)

[11] Kondo Y, Yoshikawa M, Analyst, 126, 871 (2001)

[12] Marx-Tibbon S, Willner I, J. Chem. Soc., Chem. Commun., 10, 1261 (1994)

[13] Mathewkrotz J, Shea KJ, J. Am. Chem. Soc., 118(34), 8154 (1996)

[14] Yang Z, Xu Z, Bing N, Chem. Ind. Eng. Prog., 25, 131 (2006)

[15] He X, He G, Zeng B, Sun H, Yang H, Chen S, Zhou H, Journal of Xiamen University (Natural Science), 40, 495 (2001)

[16] Zhang Y, Technology of Water Treatment, 27, 99 (2001)

[17] Zhou J, He X, Yang W, Shi H, Chemical Journal of Chinese Universities, 19, 1388 (1998)

[18] Hawkins DM, Trache A, Ellis EA, Stevenson D, Holzenburg A, Meininger GA, Reddy SM, Biomacromolecules, 7(9), 2560 (2006)

[19] Jin Y, Row KH, Korean J. Chem. Eng., 22(2), 264 (2005)

[20] Ferrer I, Lanza F, Tolokan A, Horvath V, Sellergren B, Horvai G, Barcelo D, Anal. Chem., 72, 3934 (2000)

[21] Stevenson D, Trends in Ana1ytical Chemistry, 18, 154 (1999)