Four binary polymer blends containing poly [ethylene-co-(acrylic acid)] (PEAA) as one component, and poly(4-vinyl phenol-co-2-hydroxy ethyl methacrylate) (P4VPh-co-2HEMA) or poly(2-ethyl-2-oxazoline) (PEOx) or poly(vinyl acetate-co-vinyl alcohol) (PVAc-co-VA) or poly (vinylpyrroliclone-co-vinyl acetate) (PVP-co-VAc) as the other component were prepared and used as a matrix of a series of composite materials. These binary mixtures were either partially or completely miscible within the composition range studied and were characterized by differential scanning calorimetry (DSC) and Fourier transformed infrared spectroscopy (FTIR). Carbon nanotubes (CNTs) were prepared by a thermal treatment of polyester synthesized through the chemical reaction between ethylene glycol and citric acid over an alumina boat. High resolution transmission electron microscopy (HRTEM) was used to characterize the synthesized CNTs. Films of composite materials containing CNTs were obtained after evaporation of the solvent used to prepare solutions of the four types of binary polymer blends. Young's moduli of the composites were obtained by thermomechanical analysis at room temperature. Only one glass transition temperature was detected for several compositions on both binary blends and the composite material matrices. Evidence of hydrogen bond formation was recorded for both miscible blends and composite materials. The degree of crystallinity and Young's moduli of the CNT-polymer composites increased compared to the single polymer blends. (c) 2008 Wiley Periodicals, Inc.