화학공학소재연구정보센터
Chemical Physics Letters, Vol.450, No.4-6, 426-430, 2008
Induced solvent chirality: A VCD study of camphor in CDCl3
It is shown how the presence of a chiral compound in solution induces chirality in the surrounding solvent molecules. Using Vibrational Circular Dichroism on camphor dissolved in deuterated chloroform, it is found that the C-D stretch in the latter indeed becomes VCD active. The experimental results agree with ab initio computed spectra for 1:1 associations between the solvent and solute. (c) 2007 Elsevier B.V. All rights reserved.