화학공학소재연구정보센터
Combustion and Flame, Vol.153, No.1-2, 33-44, 2008
Soret transport, unequal diffusivity, and dilution effects on laminar diffusion flame temperatures and positions
Since, according to ideal gas kinetic theory, Ludwig-Soret species transport (temperature-gradient-driven mass transport) must be simultaneously included along with nonunity Lewis numbers [D.E. Rosner, R.S. Israel, B. La Mantia, Combust. Flame 123 (2000) 547-560], we formally consider here the influence of both effects on laminar, counterflow gaseous diffusion flames in the thin flame limit. Our deliberately idealized theoretical analysis includes cases of steady/unsteady, strained/unstrained flames and formally permits the prediction of trends for the combustion of either light or heavy fuel vapors in O-2-containing streams. Our results suggest that, in cases of low- or high-molecular-weight gaseous fuels, Ludwig-Soret transport can itself introduce significant shifts in flame position and flame temperature, compared to results of the same mathematical model neglecting Soret fuel-vapor transport but including only nonunity fuel Lewis numbers. These systematic shifts (which in specific cases may have to be supplemented by additional corrections due to variable thermophysical properties) are expected to have important consequences for NO, production and/or infrared radiation emission. (C) 2008 The Combustion Institute. Published by Elsevier Inc. All rights reserved.