The copolymers of p-phenylene di{4-[2(allyloxy) ethoxy]benzoate} (p-PAEB) with n-propyl methacrylate (PMA) were synthesized. The liquid crystalline behavior and thermal properties of copolymers were studied by polarizing optical microscopy (POM), differential scanning calorimetry (DSC), X-ray diffractometer (XRD), and torsional braid analysis (TBA). The results of XRD, POM, and DSC demonstrate that the phase texture of copolymers is affected by the composition of liquid crystal units in copolymers. The POM and XRD reveal that liquid crystal monomer (p-PAEB) and copolymers of p-PAEB with PMA are all smectic phase texture. The dynamic mechanical properties of copolymers are investigated with TBA. The results indicate that the phase transition temperatures and dynamic mechanical loss peak temperature T-p of copolymers are affected by the composition of copolymers and liquid crystal cross networks. The maximal mechanical loss T-p is 114 degrees C and is decreased with added PMA. The behaviors of phase transition are affected by the crosslinking density, and it is revisable for lightly crosslinking LC polymer networks, but it is nonreversible for the densely crosslinking of LC polymer networks. (C) 2008 Wiley Periodicals, Inc.