화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.108, No.1, 76-84, 2008
Striped-pattern deterioration and morphological analysis of injection molding comprising polypropylene/ethylene-alpha-olefin rubber blends. II. Influence of heating
Unique deterioration with a striped pattern caused by thermal heating is reported for injection molding comprising polypropylene/ethylene-alpha-olefin rubber blends. This stripe is due to the formation of glossy and cloudy parts in alternation approximately perpendicular to the flow direction of the molten resin. On the surface of the cloudy part, a number of micro-objects appear. They have a dome shape about 10 mu m in diameter and 2 mu m height. Some experimental evidence indicates that the objects are composed of the rubber contained in the blends. On the other hand, only a few objects appear in the glossy region after heating. This is the reason that the stripe with the micro-objects (migrating rubber to the surface) is examined in terms of a higher order structure of injection molding with laser scanning microscopy, wide-angle X-ray scattering, and microhardness (Martens hardness). Consequently, we have concluded that this thermally deteriorated stripe depends on periodic changes in the crystallinity along the flow direction. The evidence indicates that a snakelike flow occurs during the injection process of the molding. (C) 2007 Wiley Periodicals, Inc.