화학공학소재연구정보센터
Journal of the Korean Industrial and Engineering Chemistry, Vol.20, No.4, 396-401, August, 2009
전기이중층 캐패시터 전극용 meso-pore구조의 미소구형 활성탄소 제조
Preparation of Micro-spherical Activated Carbon with Meso-porous Structure for the Electrode Materials of Electric Double Layer Capacitor
E-mail:
초록
전기이중층 캐패시터의 성능향상을 위한 전극물질로서 resorcinol-formaldehyde수지를 탄소원으로 사용하여 meso-pore 비율 52∼64%의 기공특성을 지니며 직경 2∼10 μm의 미세구형 활성탄을 제조하였다. 이 활성탄을 전기이중층에 적용한 결과, meso-pore구조의 미세구형활성탄은 전하전달저항의 저감 및 충방전율 수용능력 향상에 효과적인 영향을 나타내어 전기이중층 캐패시터의 성능향상을 위한 효과적인 전극물질이 될 수 있음을 확인할 수 있었다.
A micro-spherical activated carbon with meso-pore structure of 52∼64% and particle diameter of 2∼10 μm was prepared for the improvement electrochemical performance of activated carbon as electrode material for electric double layer capacitor. Resorcinol-formaldehyde resin was used as a carbon source in this preparation. According to electrochemical analysis of EDLC using this activated a carbon with showing effects to reduce charge transfer resistance and to increase rate capability, it was found out that micro-spherical activated carbon could be a good method as well as a material for enhancing the performance of electric double layer capacitor.
  1. Lee CT, Kim JH, Cho BW, Prospect. Ind. Chem., 2(1), 16 (1999)
  2. Osaka T, Datta M, Energy Storage Systems for Electronics, 521, Gordon and Breach Science Publishers, New York (2000)
  3. Hahn M, Koetz R, Gallay R, Siggel A, Electrochim. Acta, 52(4), 1709 (2006)
  4. Nanbu N, Ebina T, Uno H, Ishizawa S, Sasaki Y, Electrochim. Acta, 52(4), 1763 (2006)
  5. Osaka T, Liu XJ, Nojima M, J. Power Sources, 74(1), 122 (1998)
  6. Gu HB, Kim JU, Song HW, Park GC, Park BK, Electrochim. Acta, 45(8-9), 1533 (2000)
  7. Zhang B, Liang J, Xu CL, Wei BQ, Ruan DB, Wu DH, Materials Letters, 51, 539 (2001)
  8. Yoon BJ, Jeong SH, Lee KH, Kim HS, Park CG, Han JH, Chem. Phys. Lett., 388(1-3), 170 (2004)
  9. Hwang SW, Hyun SH, Journal of Non-Crystalline Solids, 347, 238 (2004)
  10. Prabaharan SRS, Vimala R, Zainal Z, J. Power Sources, 161(1), 730 (2006)
  11. Wen S, Jung M, Joo OS, Mho SI, Curr. Appl. Phys., 6(6), 1012 (2006)
  12. Mitani S, Lee SI, Saito K, Korai Y, Mochida I, Electrochim. Acta, 51(25), 5487 (2006)
  13. Liu G, Kang F, Li B, Huang Z, Chuan X, Journal of Physics and Chemistry of Solids, 67, 1186 (2006)
  14. Fang B, Wei YZ, Kumagai M, J. Power Sources, 155(2), 487 (2006)
  15. Leitner K, Lerf A, Winter M, Besenhard JO, Villar-Rodil S, Suarez-Garcia F, Martinez-Alonso A, Tascon JMD, J. Power Sources, 153(2), 419 (2006)
  16. Gryglewicz G, Machnilkowski J, -Grabowska EL, Lota G, Frackowiak E, Electrochimica Acta, 50, 1197 (2004)
  17. Merino C, Soto P, Vilaplana-Ortego E, Gomez de Salazar JM, Pico F, Rojo JM, Carbon, 43, 551 (2005)
  18. Raymundo-Pinero E, Kierzek K, Machnikowski J, Beguin F, Carbon, 44, 2498 (2006)
  19. Lin C, Ritter JA, Carbon, 35, 1271 (1997)
  20. Tamon H, Ishizaka H, Araki T, Okazaki M, Carbon, 36, 1257 (1998)
  21. Hasegawa T, Mukai SR, Shirato Y, Tamon H, Carbon, 42, 2573 (2004)
  22. Park SJ, Jung WY, J. Colloid Interface Sci., 250(1), 196 (2002)
  23. Teng H, Wang SC, Carbon, 38, 817 (2000)
  24. Hayashi J, Kazehaya A, Muroyama K, Watkinson AP, Carbon, 38, 1873 (2000)
  25. Sun JK, M.S. Dessertation, Dankook University, Seoul, Korea (2001)