Influence parameters in the ozonation of phenol wastewater treatment using bubble column reactor under continuous circulation

Manickam Matheswaran; Il Shik Moon

Journal of Industrial and Engineering Chemistry, Vol.15, No.3, 287-292, May, 2009

DOI10.1016/j.jiec.2008.12.008 Export Citation

Influence parameters in the ozonation of phenol wastewater treatment using bubble column reactor under continuous circulation

Manickam Matheswaran, and Il Shik Moon^†

Dept. of Chemical Engineering, Sunchon National University, 315 Maegok Dong, Suncheon 540-742, Chonnam, Republic of Korea

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The ozonation of phenol wastewater treatment system has been investigated with effective mass transfer between gas and liquid phase in a bubble column reactor. The designed bubble column reactor was investigated for increasing the rate of mass transfer of ozone, the rate of oxidation of phenol in the solution, the solubility and decomposition rate of ozone in the distilled water were also studied at different flow rates. The decomposition rate constants were calculated based on pseudo first order kinetics. The oxidation of phenol was investigated in order to provide the overall reaction rate constant for the reaction between ozone and phenol at 25 ℃. The influence of the operating parameters like initial phenol concentration, ozone flow rate and pH for the destruction of phenol by ozonation were studied. The pseudo first order rate constant was depending on the initial concentration of phenol solution. A comparison of TOC removal percentage between bubble column reactor and bubble diffuser using ozonation were reported.

Keywords:Ozone;Ozonation;Phenol;Kinetic rate constants;Bubble column reactor

[References]

Gurol MD, Singer PC, Water Res., 17, 1163 (1983)
Xu F, Liu C, Ozone-Sci. Eng., 12, 269 (1990)
Shin WT, Mirmiran A, Yiacoumi S, Tsouris C, Sep. Purif. Technol., 15(3), 271 (1999)
Gao MT, Hirata M, Takanashi H, Hano T, Sep. Purif. Technol., 42(2), 145 (2005)
Chiang PC, Ko YW, Liang CH, Chang EE, Chemosphere, 39, 55 (1999)
Gaddis ES, Chem. Eng. Process., 38(4-6), 503 (1999)
Mok YS, J. Ind. Eng. Chem., 11(3), 425 (2005)
Ku Y, Su WJ, Shen YS, Ozone-Sci. Eng., 18, 443 (1996)
Li KY, Kuo CH, Weeks Jr. JL, AIChE J., 25, 583 (1979)
Kim WH, Nisijima W, Baes AU, Shoto E, Okada M, Water Sci. Technol., 35, 21 (1997)
Hawash S, El-Ibiari N, El-Diwani G, Waste Manage., 10, 269 (1990)
Hoigne J, Bandar H, Ozone-Sci. Eng., 1, 73 (1979)
Takahashi N, Ozone-Sci. Eng., 12, 1 (1990)
Tanarungsun G, Kiatkittipong W, Praserthdam P, Yamada H, Tagawa T, Assabumrungrat S, J. Ind. Eng. Chem., 14(5), 596 (2008)
Pontius FW (Ed.), Water Quality and Treatment, 4th ed., American Water Works Association, McGraw-Hill, New York (1990)
Farines V, Baig S, Albet J, Molinier J, Legay C, Chem. Eng. J., 91(1), 67 (2003)
Langlais B, Reckhow DA, Brink DR, Ozone in Water Treatment: Application and Engineering, vol. 36.38, Lewis Publishers, Boca Raton, FL, 1990, p. 43
Sanchez L, Domenech X, Casado J, J. Peral, Chemosphere, 50, 1085 (2003)
Wu J, Rudy K, Spark J, Adv. Environ. Res., 4, 339 (2000)
Mahamuni NN, Pandit AB, Ultrason. Sonochem., 13, 165 (2006)

[Referenced By]

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[1] Gurol MD, Singer PC, Water Res., 17, 1163 (1983)

[2] Xu F, Liu C, Ozone-Sci. Eng., 12, 269 (1990)

[3] Shin WT, Mirmiran A, Yiacoumi S, Tsouris C, Sep. Purif. Technol., 15(3), 271 (1999)

[4] Gao MT, Hirata M, Takanashi H, Hano T, Sep. Purif. Technol., 42(2), 145 (2005)

[5] Chiang PC, Ko YW, Liang CH, Chang EE, Chemosphere, 39, 55 (1999)

[6] Gaddis ES, Chem. Eng. Process., 38(4-6), 503 (1999)

[7] Mok YS, J. Ind. Eng. Chem., 11(3), 425 (2005)

[8] Ku Y, Su WJ, Shen YS, Ozone-Sci. Eng., 18, 443 (1996)

[9] Li KY, Kuo CH, Weeks Jr. JL, AIChE J., 25, 583 (1979)

[10] Kim WH, Nisijima W, Baes AU, Shoto E, Okada M, Water Sci. Technol., 35, 21 (1997)

[11] Hawash S, El-Ibiari N, El-Diwani G, Waste Manage., 10, 269 (1990)

[12] Hoigne J, Bandar H, Ozone-Sci. Eng., 1, 73 (1979)

[13] Takahashi N, Ozone-Sci. Eng., 12, 1 (1990)

[14] Tanarungsun G, Kiatkittipong W, Praserthdam P, Yamada H, Tagawa T, Assabumrungrat S, J. Ind. Eng. Chem., 14(5), 596 (2008)

[15] Pontius FW (Ed.), Water Quality and Treatment, 4th ed., American Water Works Association, McGraw-Hill, New York (1990)

[16] Farines V, Baig S, Albet J, Molinier J, Legay C, Chem. Eng. J., 91(1), 67 (2003)

[17] Langlais B, Reckhow DA, Brink DR, Ozone in Water Treatment: Application and Engineering, vol. 36.38, Lewis Publishers, Boca Raton, FL, 1990, p. 43

[18] Sanchez L, Domenech X, Casado J, J. Peral, Chemosphere, 50, 1085 (2003)

[19] Wu J, Rudy K, Spark J, Adv. Environ. Res., 4, 339 (2000)

[20] Mahamuni NN, Pandit AB, Ultrason. Sonochem., 13, 165 (2006)