에폭시 수지로 상용화된 Nylon 6와 비스페놀-A PC 블렌드의 열적거동

Mabrouk J.M. ABDRHMAN; Liye ZHANG; Bing ZHOU; Hangquan LI

Polymer(Korea), Vol.32, No.6, 523-528, November, 2008

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에폭시 수지로 상용화된 Nylon 6와 비스페놀-A PC 블렌드의 열적거동

Thermal Behavior of Nylon 6 and Bisphenol-A Polycarbonate Blends Compatibilized with an Epoxy Resin

Mabrouk J.M. ABDRHMAN, Liye ZHANG, Bing ZHOU, and Hangquan LI^†

School of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

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Diglycidyl ether of bisphenol-A (DGEBA) was selected as a compatibilizer in Nylon 6 and bisphenol-A polycarbonate (PC) blends. SEM revealed a much finer morphology in the presence of DGEBA. The thermal properties, such as glass transition, melting point, crystallization temperature and rate, of the blends were examined using DSC. Overall, the introduction of DGEBA caused a strong dependence of these thermal properties on the composition due to compatibilization.

Keywords:Nylon 6;polycarbonate;DEGBA

[References]

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[1] Gattiglia E, Turturro A, Pedemonte E, J. Appl. Polym. Sci., 38, 1807 (1989)

[2] Gattiglia E, Turturro A, Pedemonte E, Dondero G, J. Appl. Polym. Sci., 41, 1411 (1990)

[3] Costa DA, Oliveira CMF, J. Appl. Polym. Sci., 81(10), 2556 (2001)

[4] Cortazar M, Eguiazabal J, Iruin J, Brit. Polym. J., 21, 395 (1989)

[5] Eguiazabal JI, Nazabal J, Plast. Rubber Process Appl., 14, 211 (1990)

[6] Montaudo G, Puglisi C, Samperi F, Lamantia FP, J. Polym. Sci. A: Polym. Chem., 34(7), 1283 (1996)

[7] Gattiglia E, Turturro A, Lamantia FP, Valenza A, J. Appl. Polym. Sci., 46, 1887 (1992)

[8] Kim WN, Park CE, Burns CM, J. Appl. Polym. Sci., 49, 1003 (1993)

[9] Kawahara S, Sato K, Akiyama S, J. Polym. Sci. B: Polym. Phys., 32(1), 15 (1994)

[10] Jannasch P, Wesslen B, J. Appl. Polym. Sci., 58(4), 753 (1995)

[11] Tavares MI, Castro WP, Costa DA, J. Appl. Polym. Sci., 55(8), 1165 (1995)

[12] Costa DA, Oliveira CMF, J. Appl. Polym. Sci., 69(5), 857 (1998)

[13] Costa DA, Oliveira CMF, Tavares MIB, J. Appl. Polym. Sci., 69(1), 129 (1998)

[14] Simal AL, Oriani LAG, J. Appl. Polym. Sci., 46, 1887 (1992)

[15] Wang TT, Nishi T, Macromolecules, 10, 421 (1977)

[16] Martuscelli E, Silvestre C, Gismondi C, Makromol. Chem., 186, 2161 (1985)

[17] Martuscelli E, Riva F, Sellitti C, Silvestre C, Polymer, 26, 270 (1985)

[18] Men Y, Rieger J, Eur. Polym. J., 40, 2629 (2004)

[19] Ramesh C, Gowd EB, Macromolecules, 34(10), 3308 (2001)

[20] Yamaguchi M, Gogos CG, Adv. Polym. Technol., 20(4), 261 (2001)

[21] Yamaguchi M, Todd DB, Gogos CG, Adv. Polym. Technol., 22(3), 179 (2003)

[22] Mark JE, Ed., Polymer Data Handbook, Oxford University Press, Inc., 1999