화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.25, No.4, 710-713, July, 2008
DOI10.1007/s11814-008-0116-0  Export Citation
Preparation of H5PMo10V2O40 catalyst immobilized on spherical carbon and its application to the vapor-phase 2-propanol conversion reaction
Kyung Won La, Heesoo Kim, Ji Chul Jung, Joohyung Lee, Dong Ryul Park, Sang Hee Lee, and In Kyu Song†
  • School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Shinlim-dong, Gwanak-gu, Seoul 151-744, Korea
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Spherical carbon (SC) with a diameter of ca. 9 μm was synthesized by a hydrothermal method using sucrose as a carbon precursor. The spherical carbon was then modified to have a positive charge, and thus, to provide a site for the immobilization of H5PMo10V2O40 (PMo10V2) catalyst. The PMo10V2 catalyst was immobilized on the surfacemodified spherical carbon by taking advantage of the overall negative charge of [PMo10V2O40]5.. The PMo10V2 catalyst immobilized on the spherical carbon (PMo10V2/SC) was applied to the vapor-phase 2-propanol conversion reaction. In the catalytic reaction, the PMo10V2/SC catalyst showed a higher 2-propanol conversion than the unsupported PMo10V2 catalyst. Furthermore, the PMo10V2/SC catalyst showed enhanced oxidation catalytic activity (formation of acetone) and the suppressed acid catalytic activity (formation of propylene and isopropyl ether) compared to the unsupported PMo10V2 catalyst. The enhanced oxidation activity of PMo10V2/SC catalyst was due to the fine dispersion of [PMo10V2O40]5. on the spherical carbon formed via chemical immobilization.
Keywords:Heteropolyacid Catalyst;Spherical Carbon;Chemical Immobilization;2-Propanol Conversion
  1. Song IK, Barteau MA, Korean J. Chem. Eng., 19(4), 567 (2002)
  2. Kozhevnikov IV, Catal. Rev. Sci. Eng., 37, 311 (1995)
  3. Okuhara T, Mizuno N, Misono M, Adv. Catal., 41, 113 (1996)
  4. Hwang CY, Kwak JW, Lee WY, Lee HI, Korean J. Chem. Eng., 3, 31 (1986)
  5. Hill CL, Prosser-McCartha CM, Coord. Chem. Rev., 143, 407 (1995)
  6. Misono M, Korean J. Chem. Eng., 14(6), 427 (1997)
  7. SONG IK, MOON SH, LEE WY, Korean J. Chem. Eng., 8(1), 33 (1991)
  8. Lee WY, Song IK, Lee JK, Park GI, Lim SS, Korean J. Chem. Eng., 14(6), 432 (1997)
  9. Kim HC, Moon SH, Lee WY, Chem. Lett., 447 (1991)
  10. Choi JS, Song IK, Lee WY, Korean J. Chem. Eng., 17(3), 280 (2000)
  11. Wang R, Korean J. Chem. Eng., 20(4), 659 (2003)
  12. Song IK, Barteau MA, J. Mol. Catal. A-Chem., 212(1-2), 229 (2004)
  13. Song IK, Kim HS, Chun MS, Korean J. Chem. Eng., 20(5), 844 (2003)
  14. Youn MH, Park DR, Jung JC, Kim H, Barteau MA, Song IK, Korean J. Chem. Eng., 24(1), 51 (2007)
  15. Chu WL, Yang XG, Shan YK, Ye XK, Wu Y, Catal. Lett., 42(3-4), 201 (1996)
  16. Damyanova S, Dimitrov L, Mariscal R, Fierro JLG, Petrov L, Sobrados I, Appl. Catal. A: Gen., 256(1-2), 183 (2003)
  17. Nowinska K, Formaniak R, Kaleta W, Waclaw A, Appl. Catal. A: Gen., 256(1-2), 115 (2003)
  18. Nomiya K, Murasaki H, Miwa M, Polyhedron, 5, 1031 (1986)
  19. Hasik M, Turek W, Stochmal E, Lapkowski M, Pron A, J. Catal., 147(2), 544 (1994)
  20. Pozniczek J, Kulszewicz-Bajer I, Zagorska M, Kruczala K, Dyrek K, Bielanski A, Pron A, J. Catal., 132, 311 (1991)
  21. Hasik M, Pozniczek J, Diwowarska Z, Dziembai R, Bielaski A, Pron A, J. Mol. Catal. A-Chem., 89, 329 (1994)
  22. Kim H, Jung JC, Yeom SH, Lee KY, Song IK, J. Mol. Catal. A-Chem., 248(1-2), 21 (2006)
  23. Dziembaj R, Malecka A, Piwowarska Z, Bielaski A, J. Mol. Catal. A-Chem., 112, 423 (1996)
  24. Kim H, Kim P, Lee KY, Yeom SH, Yi J, Song IK, Catal. Today, 111(3-4), 361 (2006)
  25. Kim H, Jung JC, Kim P, Yeom SH, Lee KY, Song IK, J. Mol. Catal. A-Chem., 259(1-2), 150 (2006)
  26. Wang Q, Li H, Chen L, Huang X, Carbon, 39, 2211 (2001)
  27. Miao JY, Hwang DW, Chang CC, Lin SH, Narasimhulu KV, Hwang LP, Diam. Relat. Mat., 12, 1368 (2003)
  28. Zimmerman JL, Williams R, Khabashesku VN, Margrave JL, Nano Lett., 1, 731 (2001)
  29. Kim P, Joo JB, Kim W, Kim J, Song IK, Yi J, Catal. Lett., 112(3-4), 213 (2006)
  30. O’Donnell SE, Pope MT, J. Chem. Soc.-Dalton Trans., 2290 (1976)
  31. Kim H, Jung JC, Yeom SH, Lee KY, Yi J, Song IK, Mater. Res. Bull., 42, 2132 (2007)
  32. Hu J, Li H, Huang X, Solid State Ion., 176, 1151 (2005)
  33. Kim TW, Park IW, Ryoo R, Angew. Chem.-Int. Edit., 42, 4375 (2003)
  34. Lee JK, Song IK, Lee WY, Kim JJ, J. Mol. Catal. A-Chem., 104, 311 (1996)