화학공학소재연구정보센터
Macromolecular Research, Vol.16, No.5, 404-410, July, 2008
Preparation and Characterization of Polypropylene/Waste Ground Rubber Tire Powder Microcellular Composites by Supercritical Carbon Dioxide
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In order to obtain ‘value added products’ from polypropylene (PP)/waste ground rubber tire powder(WGRT) composites, PP/WGRT microcellular foams were prepared via supercritical carbon dioxide. The effects of blend composition and processing condition on the cell size, cell density and relative density of PP/WGRT microcellular composites were studied. The results indicated that the microcellular structure was dependent on blend composition and processing condition. An increased content of waste ground rubber tire powder (WGRT) and maleic anhydride-grafted styrene-ethylene-butylene-styrene (SEBS-g-MA) reduced the cell size, and raised the cell density and relative density, whereas a higher saturation pressure increased the cell size, and reduced the cell density and relative density. With increasing saturation temperature, the cell size increased and the relative density decreased, whereas the cell density initially increased and then decreased.
  1. Suh KW, Park CP, Maurer MJ, Tusim MH, De Genova R, Broos R, Sophiea DP, Adv. Mater., 12(23), 1779 (2000)
  2. Kumar V, Cell. Polym., 12, 207 (1993)
  3. Tomasko DL, Li HB, Liu DH, Han XM, Wingert MJ, Lee LJ, Koelling KW, Ind. Eng. Chem. Res., 42(25), 6431 (2003)
  4. Collias DI, Baird DG, Borggreve RJ, Polymer, 35(18), 3978 (1994)
  5. Krause B, Sijbesma HJP, Munuklu P, van der Vegt NFA, Wessling M, Macromolecules, 34(25), 8792 (2001)
  6. Doroudiani S, Park CB, Kortschot MT, Polym. Eng. Sci., 36(21), 2645 (1996)
  7. Goel SK, Beckman EJ, Polym. Eng. Sci., 34(14), 1137 (1994)
  8. Martini-Vvedensky JE, Suh NP, Waldman FA, U.S. Patent 4,473,665 (1984)
  9. Chiou JS, Barlow JW, Paul DR, J. Appl. Polym. Sci., 30, 2633 (1985)
  10. Naguib HE, Park CB, Panzer U, Reichelt N, Polym. Eng. Sci., 42, 1481 (2002)
  11. Nayak NC, Tripathy DK, J. Mater. Sci., 37(7), 1347 (2002)
  12. Liang JZ, Li RKY, J. Appl. Polym. Sci., 77(2), 409 (2000)
  13. Jana GK, Das CK, Macromol. Res., 13(1), 30 (2005)
  14. Kum CK, Sung YT, Kim YS, Lee HG, Kim WN, Lee HS, Yoon HG, Macromol. Res., 15(4), 308 (2007)
  15. Lee SH, Balasubramanian M, Kim JK, J. Appl. Polym. Sci., 106(5), 3209 (2007)
  16. Collias DI, Baird DG, Borggreve RJ, Polymer, 35(18), 3978 (1994)
  17. Matuana LM, Park CB, Balatinecz JJ, Polym. Eng. Sci., 38(11), 1862 (1998)
  18. Lievana E, Recycling of Ground Tyre Rubber and Polyolefin Wastes by Producing Thermoplastic Elastomers, Doctoral dissertation, Argentina, 2005, Chapter 5, p. 99
  19. Matuana LM, Park CB, Balatinecz JJ, Cellul. Polym., 17, 1 (1998)
  20. Matuana LM, Park CB, Balatinecz JJ, Polym. Eng. Sci., 37, 1137 (1997)
  21. Zhang ZX, Sridhar V, Kim JK, Polym. Compos. (2007)
  22. Lee SH, Study on Dynamic Reaction on Olefinic Thermoplastic Vulcanizate Using Waste Ground Rubber Tire Powder, Doctoral dissertation, South Korea, 2006, Chapter 4, p.186
  23. Arora KA, Lesser AJ, McCarthy TJ, Macromolecules, 31(14), 4614 (1998)
  24. Stafford CM, Russell TP, McCarthy TJ, Macromolecules, 32(22), 7610 (1999)
  25. Lee KN, Lee HJ, Kim JH, Polym. Int., 49, 712 (2000)
  26. Liang MT, Wang CM, Ind. Eng. Chem. Res., 39(12), 4622 (2000)
  27. Doroudiani S, Park CB, Kortschot MT, Polym. Eng. Sci., 36(21), 2645 (1996)