The combustion characteristics of diffusion flame formed in the wake of a cylindrical stabilizer with varying fuel injection angle were studied. This study was performed by measuring the flame stability limits, lengths and temperatures of recirculation zones of flames, turbulence intensity in the wake of stabilizer, and concentration distribution of combustion gas, and by taking photographs of flames. The flame stability limits are dependent on fuel injection angle and main air velocity. The length and temperature of recirculation zone are dependent on fuel injection angle. As the length of the recirculation zone is decreased, the flame shows more stable behavior. The temperature of recirculation zone has a maximum value at the condition of theoretical mixture. The flame stability is enhanced when the temperature in the recirculation zone decreases. The turbulence intensity in the wake of stabilizer is independent of the fuel injection angle, but it is affected by stabilizer itself and main air flow condition. If the stabilization characteristics of flame is good, the concentration of C3H8 is high, but the concentration of CO2 is low at the boundary of recirculation zone. The combustion characteristics of diffusion flame can be controlled by changing the fuel injection angles. The appropriate fuel injection angle should be selected to get high combustion efficiency, high load power, low environmental pollution, and clean combustion condition of fuel.