화학공학소재연구정보센터
Korea-Australia Rheology Journal, Vol.20, No.1, 1-6, March, 2008
Effect of elasticity of aqueous xanthan gum solution with 2-amino-methyl-1-propanol on chemical absorption of carbon dioxide
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Absorption rate of carbon dioxide was measured in the aqueous xanthan gum (XG) solution in the range of 0-0.15 wt% containing 2-amino-2-methyl-1-propanol (AMP) of 0-2 kmol/m3 in a flat-stirred vessel with an impeller of 0.05 m and agitation speed of 50 rpm at 25oC and 0.101 MPa. The volumetric liquid-side mass transfer coefficient (kLa) of CO2, which was correlated with the viscosity and the elastic behavior of XG solution containing Deborah number as an empirical formula, was used to estimate the chemical absorption rate of CO2 (RA). RA, which was estimated by mass transfer mechanism based on the film theory using the physicochemical properties and the kinetics of reaction between CO2 and AMP, was compared with the measured rate. The aqueous XG solution with elastic property of non-Newtonian liquid made RA increased compared with Newtonian liquid based on the same viscosity of the solution.
  1. Danckwerts PV, Gas-Liquis Reactions, McGraw-Hill Book Co, New York, 117 (1970)
  2. Galindo E, Nienow AW, Biochem. Prog., 8, 233 (1992)
  3. Garcia-Ochoa F, Gomez E, Biochem. Eng. J., 1, 1 (1998)
  4. Herbst H, Schumpe A, Decker W, Chem. Eng. Technol., 15, 425 (1992)
  5. Kessler WR, Popovic MK, Robinson CW, Can. J. Chem. Eng., 71, 101 (1993)
  6. Metzner AB, Otter RE, AIChE J., 3, 3 (1957)
  7. Messaoudi B, Sada E, J. Chem. Eng. Jpn., 29(1), 193 (1996)
  8. Nakanoh M, Yoshida F, Ind. Eng. Chem. Process Des. Dev., 19(1), 190 (1980)
  9. Park SW, Sohn IJ, Park DW, Oh KJ, Sep. Sci. Technol., 38(6), 1361 (2003)
  10. Park SW, Kim TY, Choi BS, Lee JW, Korea-Aust. Rheol. J., 16(1), 35 (2004)
  11. Park SW, Choi BS, Lee JW, Korea-Aust. Rheol. J., 17(4), 199 (2005)
  12. Park SW, Choi BS, Lee JW, Korea-Aust. Rheol. J., 18(3), 133 (2006)
  13. Park SW, Choi BS, Lee JW, J. Ind. Eng. Chem., 13(1), 7 (2007)
  14. Pons A, Dussap CG, Gros JB, Biotechnol. Bioeng., 33, 394 (1989)
  15. Ranade VR, Ulbrecht JJ, AIChE J., 24(5), 796 (1978)
  16. Sandford A, Baird J, The polysaccharides in Molecular Biotechnology, G. O. Aspinall, Ed., Vol. 2, Academic Press, New York, 401 (1983)
  17. Song KW, Kuk HY, Chang GS, Korea-Aust. Rheol. J., 18(2), 67 (2006)
  18. Suh IS, Schumpe A, Decker W, Biotechnol. Bioeng., 39, 85 (1992)
  19. Terasaka K, Shibata H, Chem. Eng. Sci., 58(23-24), 5331 (2003)
  20. Vashitz O, Ulitzur S, Sheituch M, Chem. Eng. Sci., 43, 1883 (1988)
  21. Vashitz O, Sheituch M, Ulitzur S, Biotechnol. Bioeng., 34, 671 (1989)
  22. Yagi H, Yoshida F, Ind. Eng. Chem. Process Des. Dev., 14(4), 488 (1975)
  23. Yu WC, Astarita G, Savage DW, Chem. Eng. Sci., 40, 1585 (1985)