Inorganic Chemistry, Vol.46, No.22, 9024-9026, 2007
Titanium-manganese compound with a chiral Mn3Ti center
We have shown here for the first time a facile route to the molecular compound [Mn3Ti(mu(3)-OCH2CH2OCH3)(2) (mu-OCH2CH2OCH3)(3)(mu-Cl)Cl-2((OPr)-Pr-i)(2)] with a Mn3Ti motif, where the Ti atom is in the chiral position and the Mn atoms occupy nonchiral sites.