Silicoaluminophosphates SAPO-11 molecular sieves were synthesized from a conventional aqueous medium, a two-liquid phase medium and a HF medium, respectively, and were characterized by various methods such as XRD, SEM, pyridine-FT-IR, NH3-TPD, Si-29 MAS-NMR. The morphologies of the SAPO-11 molecular sieves obtained from the conventional aqueous medium and the two liquid-phase media exhibit pseudo-spherical aggregates ranging from 7 to 10 mu m assembled from cubic plate microcrystallites, whereas the SAPO-11 molecular sieves synthesized from the HF medium exhibit hexagonal prismatic aggregates of about 1-3 mu m length. The synthesis media used highly influenced the number and the strength of SAPO-11 acid sites. Compared to SAPO-11 obtained from conventional aqueous medium, SAPO-11 prepared from two-liquid phase media possessed a similar number of BrOnsted acid sites but a much larger number of Lewis acid sites, whereas the SAPO-11 synthesized from HF medium had a similar number of Lewis acid sites but a much lower number of BrOnsted acid sites. The 29Si MAS-NMR spectra showed that the HF could change the manner of Si incorporation into the SAPO-11 framework. The hydroisomerization of n-hexadecane on Pt/SAPO-11 samples showed that Pt/SAPO-11 obtained from the two-liquid phase media bad the largest yield of isomers. The conversion activity of n-hexadecane was dependent on the amount of BrOnsted acid of SAPO-1 I molecular sieves, while its hydrocracking activity was related to the strong acid sites of SAPO-11. (C) 2007 Elsevier B.V. All rights reserved.