Thin Solid Films, Vol.515, No.19, 7650-7653, 2007
Effect of thermal coupling on the electronic properties of hydrogenated amorphous silicon thin films deposited by electron cyclotron resonance
In photovoltaic devices, rather thin intrinsic layers of good quality materials are required and high deposition rates are a key point for a costeffective mass production. In a previous study we have shown that good quality amorphous silicon (a-Si:H) films can be deposited by matrix distributed electron cyclotron resonance (NIDECR) plasma CVD at very high deposition rates (similar to 2.5 nm/s). However, only thick films (> 1 mu in) exhibited good transport properties. A very poor thermal coupling between the substrate holder and the substrate is the main reason for such a behaviour. We present here experimental data which support this conclusion as well as the improved transport and defect-related properties of new very thin a-Si:H samples (thickness around 0.3 mu m) deposited at a higher temperature than the previous ones. (c) 2006 Elsevier B.V All rights reserved.